- POWDER METALLURGY Journal
- January 2018
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- This work focuses on the evaluation of modified surfaces on Ti produced by powder metallurgy. These newly designed surface modifications are achieved by deposition and diffusion of a stable aqueous suspension prepared in one case from micro-sized Nb powder (Ti beta-stabilizer element) and in another case from Nb plus the addition of ammonium chloride, NH4Cl, (thermo-reactive diffusion process). Different design parameters such as diffusion element (Nb or Mo), state of the Ti substrate (green or sintered) and the treatment process (diffusion or thermo-reactive diffusion) lead to all the surface-modified materials, GreenTi-Nb, SintTi-Nb and Ti-Nb-NH4Cl, GreenTi-Mo, SintTi-Mo and Ti-Mo-NH4Cl. The modified Ti surfaces present a gradient in composition and microstructure (beta / alpha+beta / alpha phases) resulting in an improvement in some of their mechanical properties: (1) higher micro-hardness in all the modified materials and (2) lower elastic modulus (more similar to that of the human bone) in those without NH4Cl.
- Materials science and engineering
- titanium; surface-modification; powder technology; microstructural-gradient; elastic modulus; hardness