In operando evidence of deoxygenation in ionic liquid gating of YBa2Cu3O7-X Articles uri icon

authors

  • PEREZ-MUÑOZ, ANA M.
  • SCHIO, PEDRO
  • POLONI, ROBERTA
  • FERNANDEZ MARTINEZ, ALEJANDRO
  • RIVERA CALZADA, ALBERTO
  • CEZAR, JULIO C.
  • SALAS COLERA, EDUARDO
  • CASTRO, GERMAN R.
  • KINNEY, JOSEPH
  • LEON, CARLOS
  • SANTAMARIA, JACOBO
  • GARCIA-BARRIOCANAL, JAVIER
  • GOLDMAN, ALLEN M.

publication date

  • January 2017

start page

  • 215

end page

  • 220

issue

  • 2

volume

  • 114

International Standard Serial Number (ISSN)

  • 0027-8424

Electronic International Standard Serial Number (EISSN)

  • 1091-6490

abstract

  • Field-effect experiments on cuprates using ionic liquids have enabled the exploration of their rich phase diagrams [Leng X, et al. (2011) Phys Rev Lett 107(2):027001]. Conventional understanding of the electrostatic doping is in terms of modifications of the charge density to screen the electric field generated at the double layer. However, it has been recently reported that the suppression of the metal to insulator transition induced in VO2 by ionic liquid gating is due to oxygen vacancy formation rather than to electrostatic doping [Jeong J, et al. (2013) Science 339(6126):1402-1405]. These results underscore the debate on the true nature, electrostatic vs. electrochemical, of the doping of cuprates with ionic liquids. Here, we address the doping mechanism of the high-temperature superconductor YBa2Cu3O7-X (YBCO) by simultaneous ionic liquid gating and X-ray absorption experiments. Pronounced spectral changes are observed at the Cu K-edge concomitant with the superconductor-to-insulator transition, evidencing modification of the Cu coordination resulting from the deoxygenation of the CuO chains, as confirmed by first-principles density functional theory (DFT) simulations. Beyond providing evidence of the importance of chemical doping in electric double-layer (EDL) gating experiments with superconducting cuprates, our work shows that interfacing correlated oxides with ionic liquids enables a delicate control of oxygen content, paving the way to novel electrochemical concepts in future oxide electronics.

subjects

  • Renewable Energies

keywords

  • electric double-layer techniques; first-principles density functional theory; high-temperature superconductivity; near-edge x-ray absorption spectroscopies; superconductor-insulator transition