Aqueous and non-aqueous Li+/H+ ion exchange in Li-0.44/La0.52TiO3 perovskite Articles uri icon

publication date

  • February 2017

start page

  • 514

end page

  • 520

issue

  • 2

volume

  • 28

International Standard Serial Number (ISSN)

  • 0921-8831

Electronic International Standard Serial Number (EISSN)

  • 1568-5527

abstract

  • The topotactic Li+/H+ exchange in Li0.44La0.52TiO3 has been studied in different aqueous and non-aqueous media with different acidity. With this purpose, aqueous hydrochloric and nitric acid solutions and benzoic acid/ethanol solution were employed. The pristine and exchanged samples have been characterized by H-1 and Li-7 MAS-NMR, TGA and XRD techniques. Aqueous hydrochloric and nitric acid solutions produce the powders degradation and the subsequent formation of Li2TiO3 and La2Ti2O7 phases. A detailed analysis of the H-1 MAS NMR spectra of exchanged samples indicate that Li+/H+ exchange reaction in pure water produced formation of LiOH at the particles surface, band at 0 ppm, that could subsequently carbonated after exposition in air. Furthermore the presence of other OH signals at 8, 6 and 2 ppm has been related to differences on octahedral Ti-O distances, produced by La/vacancy ordering in alternating planes of perovskites. In samples immersed into benzoic acid/ethanol solution results are similar, however the amount of LiOH species in particle surface is considerable lower. The exchange degree improved when increasing exchange temperature. The mechanical grinding of powders decreases the particle size improving exchange reactions; however, grinding treatments eliminated specific NMR bands of perovskite. In ground materials new H-1 NMR bands at 6 and 4 ppm were ascribed to an amorphous phase. (C) 2016 The Society of Powder Technology Japan. Published by Elsevier B.V. and The Society of Powder Technology Japan. All rights reserved.

keywords

  • llto perovskite; li+/h+ exchange; benzoic acid; h-1 and li-7 mas-nmr; li; batteries; conductivity; diffraction; cathode; water