Electronic International Standard Serial Number (EISSN)
1361-6528
abstract
The influence of increasing the core size of Ag Si core shell nanoparticles has been investigated by using the values of the linear polarization degree at a right-angle scattering configuration, ${P}_{L}(90^\circ )$. Changes in dipolar resonances and scattering directionality conditions as a function of the core radius (Rint) for a fixed shell size (${R}_{\mathrm{ext}}=230$ nm) have been analysed. An empirical formula to obtain the ratio ${R}_{\mathrm{int}}/{R}_{\mathrm{ext}}$ by monitoring the influence of the magnetic dipolar resonance in ${P}_{L}(90^\circ )$ has been found. The effect of the refractive index of the surrounding medium, mmed, in the zero backward and almost-zero forward scattering conditions has also been studied. We have weighed up the sensitivity of ${P}_{L}(90^\circ )$ to mmed. It has been demonstrated that multipolar contributions strongly influence ${P}_{L}(90^\circ )$. This influence can be used as a fast mmed estimate. In all cases, the results show that the bigger the cores, the higher the sensitivity to mmed.
Classification
subjects
Electronics
Materials science and engineering
Physics
keywords
nanoparticles; polarization; scattering; core-shell; high refractive index; sensing